Heat capacity coefficients

In most cases heat capacities are given in the form proposed by Haas & Fisher (1976):

The extrapolation of heat capacities presented in this form to high temperatures is not possible, or at the very least, problematic (Berman & Brown, 1985). Therefore Berman & Brown (1985) and Berman (1988) did a refit of the original calorimetric data using a modified form which can be extrapolated to high temperatures :

In a conservative approach, the original cp functions were used here in their validity range up to Tmax, with extrapolations only done using the form and the parameters proposed by Berman & Brown (1985).

empty	a	b*10^3	c*10^6	d*10^-3	e*10^-4	f*10^-6	g*10^-7	from	to	empty
akermanite	445.110	-51.463	21.857	-3.7937	0	0	0	298	1100	Robie et al. (1979)
akermanite	389.640	0	0	-2.9656	0	0	-18.333	1100	1800	Berman & Brown (1985)
albite	583.940	-92.852	22.722	-6.4242	0	1.6780	0	298	1400	Hemingway et al. (1981)
almandine	292.7397	346.520	-153.160	0.71627	0	-7.2125	0	298	1000	Bohlen et al. (1986)
almandine	723.000	-26.775	0	-6.0436	0	-1.9921	0	1000	1800	Holland & Powell (1990)
analbite	671.370	-146.710	36.586	-7.9736	0	3.1740	0	298	1400	Hemingway et al. (1981)
analcite	571.830	0	0	-7.1887	0	0	149.306	298	1800	Berman & Brown (1985)
andalusite	277.306	-6.588	0	-2.2656	0	-1.9141	0	298	1800	Hemingway et al. (1991)
andradite	809.240	-70.250	0	-7.4030	0	-0.6789	0	298	1250	Robie et al. (1987)
anorthite	800.971	-292.900	105.663	-9.44981	0	3.18591	0	298	1250	Hemingway et al. (1982)
anorthite	439.370	0	0	-3.7341	0	0	-31.702	1250	1800	Berman & Brown (1985)
anthophyllite	1259.938	18.884	0	-8.1274	0	-11.6427	0	298	1200	Hemingway (1991)
antigorite	9011.990	0	0	-63.9810	0	-145.9624	1907.022	298	1800	Berman & Brown (1985)
aragonite	81.533	45.673	0	0	0	-1.1405	0	298	600	Robie et al. (1979)
aragonite	166.620	0	0	-1.4994	0	0	5.449	600	1800	Berman & Brown (1985)
boehmite	205.721	-34.921	0	-2.63527	0	1.02666	0	298	700	Hemingway et al. (1991)
brucite	102.220	15.107	0	0	0	-2.6172	0	298	500	Robie et al. (1979)
brucite	136.840	0	0	-0.5371	0	-4.3619	55.269	500	1800	Berman & Brown (1985)
CaAl-pyroxene	322.848	0	0	-2.18582	0	-2.72024	0	298	1800	Hemingway et al. (1982)
calcite	99.715	26.920	0	0	0	-2.1576	0	298	650	Robie et al. (1979)
calcite	193.240	0	0	-2.0409	0	0	19.946	650	1800	Berman & Brown (1985)
carpholite	667.800	-12.559	0	-6.4400	0	-1.1671	0	298	1800	Holland & Powell (1990)
chloritoid	484.600	-13.808	0	-4.7622	0	-0.1989	0	298	1800	Holland & Powell (1990)
chrysotile	1079.540	0	0	-6.1446	0	-28.9252	394.752	298	1800	Berman & Brown (1985)
clinochlore	1214.280	0	0	-11.2171	0	0	-125.625	298	1800	Berman (1988)
clinoenstatite	411.120	-25.592	0	-4.5954	0	2.3852	0	298	1600	Robie et al. (1979)
clinozoisite	834.6220	-39.6894	0	-8.14875	0	0	0	298	900	Hemingway et al. (1982)
clinozoisite	751.370	0	0	-6.5857	0	-1.9308	5.143	900	1800	Berman & Brown (1985)
coesite	94.9070	0	0	-0.7673	0	-0.5279	2.627	298	1800	Berman (1988)
cordierite	821.340	43.339	0	-5.0003	0	-8.2112	0	298	1700	Robie et al. (1979)
corundum	233.004	-39.1826	9.4441	-2.46518	0	0	0	298	1800	Hemingway et al. (1982)
a-cristobalite	-4159.600	2548.000	0	71.6800	0	-62.8590	0	298	523	Robie et al. (1979)
b-cristobalite	72.753	1.3004	0	0	0	-4.1320	0	523	1800	Robie et al. (1979)
deerite	3164.400	-27.883	0	-26.7210	0	-5.0391	0	298	1800	Holland & Powell (1990)
diaspore	150.556	0	0	-1.73002	0	0.24307	0	298	650	Hemingway et al. (1982)
diaspore	143.240	0	0	-1.5404	0	-0.3231	6.463	650	1800	Berman & Brown (1985)
diopside	191.820	83.079	-21.718	0	0	-4.2795	0	298	1600	Robie et al. (1979)
dolomite	547.880	-167.590	77.076	-6.5479	0	2.8400	0	298	900	Robie et al. (1979)
dolomite	368.020	0	0	-3.7508	0	0	18.079	900	1800	Berman & Brown (1985)
edenite	1264.900	24.090	0	-7.7040	0	-12.5600	0	298	1800	Holland & Powell (1990)
enstatite	356.200	-2.990	0	-3.1850	0	-0.5970	0	298	1800	Holland & Powell (1985)
fayalite	248.930	0	0	-1.9239	0	0	-13.910	298	1800	Berman (1988)
ferrocordierite	851.500	44.724	0	-5.6234	0	-6.6450	0	298	1800	Holland & Powell (1990)
ferroglaucophane	1762.900	-118.992	0	-20.2071	0	9.4237	0	298	1800	Holland & Powell (1990)
ferroactinolite	1290.000	29.991	0	-8.9470	0	-8.4475	0	298	1800	Holland & Powell (1990)
ferrosilite	338.120	0	0	-2.3860	0	-4.1944	58.506	298	1800	Berman (1988)
forsterite	87.360	87.170	-22.370	0.8436	0	-3.6990	0	298	1800	Robie et al. (1979)
gehlenite	588.351	-134.306	38.9086	-6.27433	0	1.51047	0	298	1500	Hemingway & Robie (1984)
gehlenite	373.090	0	0	-2.2768	0	-4.7785	47.791	1500	1800	Berman & Brown (1985)
glaucophane	1717.500	-121.070	0	-19.272	0	7.0750	0	298	1800	Holland (1988)
grossularite	985.362	-193.287	33.5314	-10.7077	0	1.7708	0	298	850	Hemingway et al. (1982)
grossularite	573.430	0	0	-2.0394	0	-18.8872	231.931	850	1800	Berman (1988)
grunerite	1383.100	30.669	0	-11.2576	0	-4.2247	0	298	1800	Holland & Powell (1990)
hedenbergite	310.460	12.570	0	-2.03993	0	-1.84604	0	298	1800	Haselton et al. (1987)
a-hematite	-5750.0704	1177.9302	0	257.6669	-370.2932	333.8738	-2003.3214	298	950	Robie et al. (1979)
b-hematite	-1095.700	272.670	0	33.9600	0	-102.3900	0	950	1800	Robie et al. (1979)
hercynite	238.00	6.820	0	-1.8627	0	-0.9031	0	298	1800	Holland & Powell (1990)
ilmenite	262.661	-79.9893	33.8771	-2.53794	0	0.3827	0	298	1650	Anovitz et al. (1985)
a-iron	14.100	29.7064	0	0	0	0.17991	0	298	800	Barin et al. (1977)
a-iron	-263.454	255.810	0	0	0	61.9230	0	800	1000	Barin et al. (1977)
a-iron	-641.905	696.339	0	0	0	0	0	1000	1042	Barin et al. (1977)
a-iron	1946.255	-1787.497	0	0	0	0	0	1042	1060	Barin et al. (1977)
a-iron	-561.932	334.143	0	0	0	291.2110	0	1060	1184	Barin et al. (1977)
g-iron	23.991	8.360	0	0	0	0	0	1184	1665	Barin et al. (1977)
jadeite	301.130	10.143	0	-2.0551	0	-2.2393	0	298	1000	Robie et al. (1979)
jadeite	311.290	0	0	-2.0051	0	-5.3503	66.257	1000	1800	Berman & Brown (1985)
kalsilite	242.000	-4.482	0	-1.9358	0	-0.8958	0	298	1800	Holland & Powell (1990)
kaolinite	1498.350	-270.841	0	-16.5573	0	2.9839	0	298	550	Hemingway et al. (1982)
kaolinite	1046.460	0	0	-8.8534	0	-4.4886	18.462	550	1800	Berman & Brown (1985)
kyanite	279.435	-7.124	0	-2.28936	0	-2.0556	0	298	1800	Hemingway et al. (1991)
larnite	249.689	0	0	-2.09429	0	0	0	298	970	Hemingway et al. (1982)
a`-larnite	161.620	0	18.8970	0	0	0	0	970	1800	Hemingway et al. (1982)
laumontite	515.469	186.060	0	0	0	-6.8743	0	298	750	Helgeson et al. (1978)
lawsonite	877.642	-73.1378	17.2830	-11.4045	0	7.7004	0	298	1800	Berman & Brown (1985)
leucite (tetra.)	148.420	134.250	0	0	0	-2.1645	0	298	955	Robie et al. (1979)
leucite (cubic)	196.470	27.666	0	0	0	12.261	0	955	1800	Robie et al. (1979)
lime	71.6851	-6.16496	2.23862	-0.43199	0	-0.25558	0	298	1000	Hemingway et al. (1982)
lime	58.790	0	0	-0.1339	0	-1.1471	10.298	1000	1800	Berman & Brown (1985)
magnesite	81.119	52.254	0	0	0	-1.8320	0	298	800	Robie et al. (1979)
magnesite	194.080	0	0	-2.1210	0	-0.1533	17.491	800	1800	Berman & Brown (1985)
a-magnetite	-21637.1243	4591.0951	0	928.8223	-1299.0655	1123.9752	-6481.8403	298	848	Robie et al. (1979)
b-magnetite	96.823	52.733	00	0	0	56.4130	0	848	1800	Robie et al. (1979)
margarite	826.504	-50.291	0	-8.42744	0	0	0	298	1200	Hemingway et al. (1982)
meionite	1316.000	64.990	0	-8.9320	0	-8.9630	0	298	1200	Holland & Powell (1985)
merwinite	453.620	0	00	-3.2500	0	0	-34.423	298	1800	Berman & Brown (1985)
microcline	759.550	-217.110	64.333	-9.5268	0	4.7632	0	298	1100	Hemingway et al. (1981)
monticellite	231.404	-0.85314	-1.333	-1.62342	0	-1.24743	0	298	1500	Sharp et al. (1986)
mullite	754.550	-29.426	0	-6.5757	0	-3.4541	0	298	1800	Robie et al. (1979)
muscovite	917.670	-81.110	0	-10.348	0	2.8341	0	298	1000	Robie et al. (1979)
muscovite	651.490	0	0	-3.8732	0	-18.5232	274.247	1000	1800	Berman & Brown (1985)
Na-phlogopite	773.500	-40.229	0	-6.5126	0	-2.5979	0	298	1800	Holland & Powell (1990)
a-nepheline	27.740	295.400	0	0	0	0	0000	298	467	Robie et al. (1979)
b-nepheline	112.090	67.110	00	0	0	0	0	467	1180	Robie et al. (1979)
g-nepheline	172.000	5.520	0	0	0	0	0	1180	1525	Robie et al. (1979)
nickel	11.110	37.872	0	0	0	0.32281	0	298	600	Holmes et al. (1986)
nickel	-2254.156	2535.030	0	0	0	276.4775	0	600	631	Holmes et al. (1986)
nickel	-70.754	90.924	0	0	0	18.5720	0	631	700	Holmes et al. (1986)
nickel	20.688	9.9716	0	0	0	1.5223	0	700	1728	Holmes et al. (1986)
a-NiO	-27.552	169.040	0	0	0	1.9083	0	298	525	Holmes et al. (1986)
b-NiO	-37.715	175.730	0	0	0	0	0	525	565	Holmes et al. (1986)
g-NiO	58.417	-7.1212	0	0	0	0	0	565	800	Holmes et al. (1986)
g-NiO	35.109	15.1064	0	0	0	3.9426	0	800	1200	Holmes et al. (1986)
g-NiO	45.518	12.038	0	0	0	00	0	1200	2000	Holmes et al. (1986)
paragonite	691.910	0	0	-5.3320	0	-11.0225	162.829	298	1800	Berman & Brown (1985)
pargasite	1280.200	22.997	0	-8.0658	0	-12.3595	0	298	1800	Holland & Powell (1990)
periclase	65.211	-1.2699	0	-0.38724	0	-0.46185	0	298	1800	Robie et al. (1979)
phlogopite	872.130	-77.250	0	-8.6006	0	0.3575	0	298	900	Robie & Hemingway (1984)
phlogopite	610.380	0	0	-2.0838	0	-21.5330	284.104	900	1800	Berman (1988)
prehnite	946.022	-115.065	0	-10.5605	0	2.75523	0	298	800	Hemingway et al. (1982)
prehnite	652.390	0	0	-4.2318	0	-12.1193	160.044	800	1800	Berman & Brown (1985)
pumpellyite	1720.800	-24.928	0	-14.6203	0	-5.9987	0	298	1800	Holland & Powell (1990)
pyrope	802.580	-95.795	0	-7.2873	0	-2.3522	0	298	800	Robie et al. (1979)
pyrope	535.550	0	0	-1.2414	0	-19.6256	217.002	800	1800	Berman & Brown (1985)
pyrophyllite	1454.510	-792.186	397.189	-17.7428	0	6.06936	0	298	750	Hemingway et al. (1982)
pyrophyllite	665.930	0	0	-5.8974	0	-4.9799	66.181	750	1800	Berman & Brown (1985)
a-quartz	81.1447	18.2834	5.4058	-0.69846	0	-0.18099	0	298	844	Hemingway (1987)
b-quartz	57.9588	9.33019	0	0	0	1.83471	0	844	1800	Hemingway (1987)
rankinite	473.209	-42.071	0	-4.3188	0	0.33972	0	298	1200	Hemingway et al. (1982)
rutile	77.840	0	0	0	0	-3.3678	40.294	298	1800	Berman & Brown (1985)
sanidine	693.370	-171.700	49.188	-8.3054	0	3.4622	0	298	1250	Hemingway et al. (1981)
sanidine	395.490	0	0	-2.4159	0	-8.5454	121.491	1250	1800	Berman & Brown (1985)
sapphirine	1545.988	158.2389	0	0	0	-46.3671	0	298	1300	Kiseleva (1976)
sillimanite	280.190	-6.900	0	-2.39937	0	-1.37573	0	298	2000	Hemingway et al. (1991)
sphene	176.730	23.852	0	0	0	-3.9905	0	298	1250	Robie et al. (1979)
sphene	234.620	0	0	-1.0403	0	-5.1183	59.146	1250	1800	Berman & Brown (1985)
spinel	226.495	0	0	-1.49101	0	-2.71281	15.353	298	1800	estimated
spurrite	99.715	453.264	-163.002	3.31276	0	-6.87774	0	298	1300	estimated
staurolite	3050.4566	0	0	-30.8215	0	10.3698	-278.2959	298	1800	Hemingway & Robie (1984)
talc	664.110	0	0	-5.1872	0	-2.1472	32.737	298	1300	Berman & Brown (1985)
tilleyite	672.639	11.769	0	-4.3188	0	-3.97548	0	298	1300	estimated
tremolite	2102.740	-471.689	111.464	-24.1463	0	7.631	0	298	1600	Robie et al. (1979)
a-tridymite	75.370	0	0	0	0	-5.9581	95.825	298	432	Berman (1988)
b-tridymite	74.904	3.0999	0	-0.23669	0	-1.174	0	432	1800	Robie et al. (1979)
vesuvianite	3062.270	352.290	0	0	0	-87.697	0	298	1600	Valley et al. (1985)
wairakite	420.074	186.060	0	0	0	-6.8743	0	298	1000	Helgeson et al. (1978)
wollastonite	289.066	0	0	-1.09104	0	-8.7878	120.178	298	995	Richet et al. (1991)
wollastonite	270.056	0	0	-0.63956	0	0	0	995	1398	Richet et al. (1991)
c-wollastonite	309.318	0	0	-2.0178	0	-1.4708	0	1398	1800	Richet et al. (1991)
wuestite	-19.296	30.165	0	1.5009	0	-2.5333	0	298	1652	Robie et al. (1979)
zoisite	834.622	-39.6894	0	-8.14875	0	0	0	298	900	Hemingway et al. (1982)
zoisite	751.370	0	0	-6.5857	0	-1.9308	5.143	900	1800	Berman & Brown (1985)
carbondioxide	87.820	-2.6442	0	-0.99886	0	0.70641	0	298	1800	Robie et al. (1979)
water	10.4381	25.955	-4.46885	0.29919	0	-0.13108	0	298	1800	Robie et al. (1979)
oxygen	48.318	-0.69132	0	-0.42066	0	0.49923	0	298	1800	Robie et al. (1979)